Improvement of P-Type Contact in WSe<sub>2</sub> Field-Effect Transistors via Defect Engineering
Heng Zhang, Jialei Miao, Chengchun Zhang, Xinlong Zeng, Tianjiao Zhang, Tingting Chen, J. F. Wu, Kaige Gao, Wei Xu, Xiaowei Zhang, Yuda Zhao
Abstract
Two-dimensional (2D) material-based p-channel field-effect transistors (FETs) are key elements for the realization of complementary metal-oxide-semiconductor (CMOS) technology. WSe 2, as the primary material for p-channel FETs, is suffering from intrinsic atomic defects and extrinsic defects during metal deposition, making it difficult to form high-quality metal–semiconductor contact interfaces. This leaves significant space for improvement in the performance of p-channel FETs. In this work, we propose an effective defect optimization strategy, focusing on the contact interface. The trifluoromethyl thianthrenium triflate (TTT) molecule treatment on WSe 2 increases the hole density, induces the defect passivation, and enhances the hole transport efficiency. The high work-function semimetal TiS 2 effectively prevents damage caused by metal deposition and facilitates efficient hole transport. The optimized WSe 2 -CF 3 -TiS 2 FET achieves a high hole mobility of ∼147 cm 2 /V·s and demonstrates excellent stability at 200 °C.