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Luminescent hybrid halides with various centering metal cations (Zn, Cd and Pb) and diverse structures

Liubing Fan, Shiqiang Hao, Shihui He, Xusheng Zhang, Mingyang Li, Christopher Wolverton, Jing Zhao, Quanlin Liu

2023Dalton Transactions11 citationsDOIOpen Access PDF

Abstract

is assigned to STEs. Density functional theory calculations reveal that the three compounds adopt a direct band gap. This work enriches our understanding of the structure types of hybrid metal halides while revealing their diverse emission mechanisms.

Topics & Concepts

Triclinic crystal systemHalideMetal halidesPhotoluminescenceOctahedronMetalCrystal structureLuminescenceChemistryCrystallographyThermal stabilityBand gapExcitonGroup (periodic table)Materials scienceInorganic chemistryOptoelectronicsOrganic chemistryPhysicsQuantum mechanicsPerovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyLuminescence Properties of Advanced Materials
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