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Reactivity of quinone methides with carbenes generated from α-diazocarbonyl compounds and related compounds

Sharma Happy, Mohammad Junaid, Dongari Yadagiri

2022Chemical Communications19 citationsDOI

Abstract

-generated transient intermediates undergo cycloannulation reactions, metathesis-type reactions, 1,6-conjugate addition reactions, cyclopropanation reactions, and many other transformations to access nitrogen- and oxygen-containing heterocyclic compounds and beyond. The reactivity of quinone methides and carbenes is observed in various metal catalysts, Brønsted-acids, Lewis acids, phase transfer catalysts, additives, and visible-light-induced transformations.

Topics & Concepts

QuinoneReactivity (psychology)ChemistryCyclopropanationCatalysisOrganic chemistryCombinatorial chemistryMetathesisPolymerizationPathologyPolymerMedicineAlternative medicineSynthesis of Indole DerivativesClick Chemistry and ApplicationsCatalytic C–H Functionalization Methods
Reactivity of quinone methides with carbenes generated from α-diazocarbonyl compounds and related compounds | Litcius