Design of a Novel Near-Infrared Luminescence Material Li<sub>2</sub>Mg<sub>3</sub>TiO<sub>6</sub>:Cr<sup>3+</sup> with an Ultrawide Tuning Range Applied to Near-Infrared Light-Emitting Diodes
Tao Tan, Shangwei Wang, Jiangyue Su, Weihong Yuan, Haiyan Wu, Ran Pang, Jiutian Wang, Chengyu Li, Hongjie Zhang
Abstract
Generally, crystal field engineering is an important means to regulate Cr3+ luminescence in near-infrared (NIR) phosphors. Host cation substitutions, including single substitutions, double substitutions, and even multiple substitutions, are widely used as a common means to modify the crystal field of Cr3+-activated phosphors. However, the tunable range using this strategy is usually limited because it is susceptible to the limitation of the host and its initial structure. In this work, we designed and synthesized a new type of controllable NIR-emitting phosphor Li2Mg3TiO6:Cr3+ using a new Cr3+ luminescent ion substitution strategy in which a double Cr3+ ion unit [Cr3+–Cr3+] was employed to replace a [Mg2+–Ti4+] unit to balance the charge. Just by changing the concentration of Cr3+, the NIR emission peak of the phosphor can be regularly adjusted from 720 to 920 nm, and the full width at half maximum reaches 258 nm. The internal quantum efficiency and external quantum efficiency of the Li2Mg3TiO6:0.03Cr3+ sample are measured to be 72.1 and 28.1%, respectively. An NIR phosphor-converted light-emitting diode (pc-LED) is fabricated by the LMT:Cr3+ phosphor and a blue chip, and the radiant fluxes of 31.09 mW@(3 V ∼ 100 mA) and 71.56 mW@(3 V ∼ 420 mA) are achieved. The results confirmed that the luminescence material has great application potential in the field of NIR spectroscopy.