Carbon dioxide-promoted palladium-catalyzed dehydration of primary allylic alcohols: access to substituted 1,3-dienes
Yankai Huang, Wen‐Zhen Zhang, Ke Zhang, Wen-le Wang, Xiao‐Bing Lu
Abstract
A carbon dioxide promoted dehydration reaction of primary allylic alcohols gives synthetically important substituted 1,3-dienes in good yields under milder conditions compared with the reaction using a heterogeneous catalyst or carbon monoxide.
Topics & Concepts
ChemistryAllylic rearrangementDehydrationCatalysisCarbon monoxidePrimary (astronomy)Carbon dioxidePalladiumOrganic chemistryPhysicsAstronomyBiochemistryCarbon dioxide utilization in catalysisAsymmetric Hydrogenation and CatalysisCatalytic C–H Functionalization Methods