Towards opto-structural parameters to enhance the circularly polarized luminescence brightness of Eu<sup>III</sup> β-diketone complexes with chiral auxiliary ligands
Isabela M.S. Diogenis, Airton G. Bispo‐Jr, Rodrigo V. Pirovani, Leonardo F. Saraiva, Fábio C. Gozzo, Carlos Roque D. Correia, Ítalo Odone Mazali, René A. Nome, Fernando A. Sigoli
Abstract
Tuning the overall emission quantum yield ( ϕ LLn), dissymmetry factor ( g lum ), as well as CPL brightness by changing the electronic structure and microsymmetry of the Eu III coordination polyhedron.
Topics & Concepts
LuminescenceBrightnessMaterials scienceCrystallographyPhotochemistryOpticsPhysicsOptoelectronicsChemistryLanthanide and Transition Metal ComplexesSynthesis and Properties of Aromatic CompoundsMagnetism in coordination complexes