Hg<sub>2</sub>(SeO<sub>3</sub>)(SO<sub>4</sub>): the first sulfate selenite with large birefringence explored from d<sup>10</sup>transition metal compounds
Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao
Abstract
Hg 2 (SeO 3 )(SO 4 ), explored in the d 10 TM–Se( iv )–SO 4 system, features the first metal sulfate selenite with a large birefringence of up to 0.133 and 0.126 at 532 and 1064 nm, respectively.
Topics & Concepts
SeleniumBirefringenceSulfateTransition metalMaterials scienceMetalInorganic chemistryAnalytical Chemistry (journal)ChemistryNuclear chemistryOpticsOrganic chemistryMetallurgyPhysicsCatalysisCrystal Structures and PropertiesSolid-state spectroscopy and crystallographyNonlinear Optical Materials Research