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Ultrafast Surface Plasmon Probing of Interband and Intraband Hot Electron Excitations

Péter Sándor, Béla Lovász, Judit Budai, Zsuzsanna Pápa, Péter Dombi

2024Nano Letters10 citationsDOIOpen Access PDF

Abstract

Upon the interaction of light with metals, nonthermal electrons are generated with intriguing transient behavior. Here, we present femtosecond hot electron probing in a noveloptical pump/plasmon probe scheme. With this, we probed ultrafast interband and intraband dynamics with 15 nm interface selectivity, observing a two-component-decay of hot electron populations. Results are in good agreement with a three-temperature model of the metal; thus, we could attribute the fast (∼100 fs) decay to the thermalization of hot electrons and the slow (picosecond) decay to electron-lattice thermalization. Moreover, we could modulate the transmission of our plasmonic channel with ∼40% depth, hinting at the possibility of ultrafast information processing applications with plasmonic signals.

Topics & Concepts

PlasmonFemtosecondUltrashort pulsePicosecondElectronThermalisationSurface plasmonMaterials scienceFree electron modelAtomic physicsHot electronMolecular physicsOptoelectronicsChemistryPhysicsOpticsLaserQuantum mechanicsPlasmonic and Surface Plasmon ResearchGold and Silver Nanoparticles Synthesis and ApplicationsPhotonic and Optical Devices
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