The Linkage‐Moderated Covalent Organic Frameworks with C=N and NN on Charge Transfer Kinetics Towards the Robust Photocatalytic Hydrogen Activity
Haiyang Wu, Xuan He, Xing Du, Daheng Wang, Weixin Li, Hui Chen, Wei Fang, Lei Zhao
Abstract
Abstract Since the linkages structured in covalent organic frameworks (COFs) usually impact the charge transfer behavior during photocatalytic hydrogen evolution reaction (pc‐HER), linkage dependence on charge transfer kinetics should be further claimed. Herein, COFs with N‐based linkages and pyrene‐based building nodes are constructed to enable us to obtain new clues about the charge transfer behavior and evolution tendency relevant to linkages at a molecular level for pc‐HER. It is demonstrated that photo‐excited electrons preferably move to the N sites in C=N linkage for pc‐HER and are trapped around NN linkage as well. A high electron transfer rate does not point to high photocatalytic activity directly, while a small difference between the electron transfer rate and electron recombination rate Δ k CT − CR predicts the inefficiency of charge transfer in Azod‐COFs. Contrarily, large value of Δ k CT − CR in the case of Benzd‐COFs, demonstrats an unimpeded charge transfer process to result in boosted pc‐HER rate (2027.3 µmol h −1 g −1 ). This work offers a prominent strategy for the reasonable design of efficient photocatalysts at the molecular level for structural regulation and achieves an efficient charge transfer process for the pc‐HER process.