Fragrance carriers obtained by encapsulation of volatile aromas into zeolite structures
Susana P. G. Costa, O.S.G.P. Soares, Cristina Almeida Aguiar, Isabel C. Neves
Abstract
Encapsulation of fragrances into porous materials is a technique to preserve or mask the odor of aroma compounds as well as to enhance their thermal and oxidative stability. There is great interest in studying the potential of essential oil-derived fragrance carriers using low-cost materials such as zeolitic structures for healthcare, food, textiles or agricultural applications. Two zeolite structures, faujasite (FAU) and mordonite (MOR) were used as carriers for encapsulation of different fragrances present in essential oils, in order to prepare stable fragrance carriers. To this purpose, commercial vanillin (Van) was encapsulated in NaMOR, commercial D-limonene (Lim) and cinnamaldehyde (Cinn), extracted from cinnamon stick, were encapsulated into NaY and NaX, respectively, and methyl anthranilate (MA), a synthetized fragrance with a fruity grape scent, was encapsulated in NaY. The retention of fragrances in zeolite structures increased in the order NaX < NaY < MOR for cinnamaldehyde, limonene, methyl anthranilate or vanillin. The most promising fragrance carriers prepared, MA@NaY and Van@MOR, were monitored for 24 months, and fragrances release was determined by TGA analysis, being 64.5 % for Van@MOR and 63.2 % for MA@NaY. A zero-order desorption kinetic model was determined for both fragrance carriers.