Litcius/Paper detail

A Multiple Chirality Switching Device for Spatial Light Modulators

Guojian Yang, Yang Yu, Baige Yang, Tong Lu, Yiru Cai, Hang Yin, Huiqi Zhang, Ning‐Ning Zhang, Li Li, Yu‐Mo Zhang, Sean Xiao‐An Zhang

2020Angewandte Chemie International Edition26 citationsDOI

Abstract

A new and simple strategy towards electric-field-driven multiple chirality switching device has been designed and fabricated by combining a newly synthesized base-responsive chiroptical polymer switch (R-FLMA) and p-benzoquinone (p-BQ) via proton-coupled electron transfer (PCET) mechanism. Clear and stable triple chirality states (silence, positive, negative) of this device in visible band can be regulated reversibly (>1000 cycles) by adjusting voltage programs. Furthermore, such chiral switching phenomena are also accompanied by apparent changes of color and fluorescence. More importantly, the potential application of this device for a spatial light modulator has also been demonstrated.

Topics & Concepts

Chirality (physics)Materials scienceMolecular switchElectric fieldVoltageHelix (gastropod)OptoelectronicsOptical switchPhysicsMoleculeQuantum mechanicsNambu–Jona-Lasinio modelQuarkSnailChiral symmetry breakingBiologyEcologyPhotoreceptor and optogenetics researchPhotochromic and Fluorescence ChemistryLuminescence and Fluorescent Materials