Suppression of self-stratification in colloidal mixtures with high Péclet numbers
Malin Schulz, R. H. G. Brinkhuis, Carol Crean, Richard P. Sear, Joseph L. Keddie
Abstract
The non-equilibrium assembly of bimodal colloids during evaporative processes is an attractive means to achieve gradient or stratified layers in thick films. Here, we show that the stratification of small colloids on top of large is prevented when the viscosity of the continuous aqueous phase is too high. We propose a model where a too narrow width of the gradient in concentration of small colloids suppresses the stratification.
Topics & Concepts
Stratification (seeds)ColloidAqueous solutionChemical physicsConcentration gradientViscosityColloidal particleMaterials scienceChemistryThermodynamicsChromatographyPhysicsPhysical chemistryBiologySeed dormancyBotanyGerminationDormancynanoparticles nucleation surface interactionsFluid Dynamics and Thin FilmsPhase Equilibria and Thermodynamics