One to Find Them All: A General Route to Ni(I)–Phenolate Species
Alessandro Bismuto, Patrick Müller, Patrick Finkelstein, Nils Trapp, Gunnar Jeschke, Bill Morandi
Abstract
electronic structure for all complexes involved. Overall, this new synthetic approach offers exciting opportunities for the discovery of new stoichiometric and catalytic reactivity as well as the mechanistic elucidation of Ni-based catalytic cycles.
Topics & Concepts
ChemistryNickelCatalysisLigand (biochemistry)TrifluoromethanesulfonateTrimethylsilylCationic polymerizationHomogeneous catalysisReactivity (psychology)StereochemistryCombinatorial chemistryMedicinal chemistryOrganic chemistryMedicineBiochemistryPathologyAlternative medicineReceptorCatalytic C–H Functionalization MethodsOrganometallic Complex Synthesis and CatalysisAsymmetric Hydrogenation and Catalysis