Substitution lability of the perfluorinated Cp* ligand in Rh(<scp>i</scp>) complexes
Joshua Parche, Susanne M. Rupf, Robin Sievers, Moritz Malischewski
Abstract
ligand can be displaced. Furthermore, the newly synthesized compounds represent rare examples of rhodium complexes containing fluorinated pyridines as ligands.
Topics & Concepts
LabilityRhodiumChemistryLigand (biochemistry)Reactivity (psychology)Cationic polymerizationPyridineMedicinal chemistryAcetonitrileStereochemistryPolymer chemistryOrganic chemistryReceptorCatalysisMedicineAlternative medicineBiochemistryPathologyFluorine in Organic ChemistryOrganometallic Complex Synthesis and CatalysisCyclopropane Reaction Mechanisms