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Quantitative Localized Analysis Reveals Distinct Exosomal Protein-Specific Glycosignatures: Implications in Cancer Cell Subtyping, Exosome Biogenesis, and Function

Yuna Guo, Jing Tao, Yiran Li, Yimei Feng, Huangxian Ju, Zhongfu Wang, Lin Ding

2020Journal of the American Chemical Society90 citationsDOI

Abstract

-acetylgalactosamine (Gal/GalNAc). In combination with sialic acid (Sia) cleavage manipulation for the exposure of originally capped Gal/GalNAc, QLA has revealed distinct MUC1-specific sialylation capping ratios for MCF-7 and MDA-MB-231 exosomes, as well as when compared to parent cells. These findings suggest a useful noninvasive indicator for subtyping cancer cells and exosome secretion as a likely venue for the preservation of cellular compositional and functional integrity. The QLA method also permits dynamic monitoring of changes in the exosomal MUC1-specific sialylation capping ratio, enabling the distinction of biogenesis pathways of exosomes.

Topics & Concepts

MicrovesiclesExosomeChemistryBiogenesisGlycanCell biologySialic acidMUC1SubtypingNanoparticle tracking analysisFunction (biology)BiochemistryMucinGlycoproteinBiologymicroRNAComputer scienceGeneProgramming languageExtracellular vesicles in diseaseRNA Interference and Gene DeliveryAnodic Oxide Films and Nanostructures