Chemical Impact of Stratospheric Alumina Particle Injection for Solar Radiation Modification and Related Uncertainties
Sandro Vattioni, Beiping Luo, Aryeh Feinberg, Andrea Stenke, Christof Vockenhuber, Rahel Weber, J. A. Dykema, Ulrich K. Krieger, Markus Ammann, Frank N. Keutsch, Thomas Peter, Gabriel Chiodo
Abstract
Abstract Compared to stratospheric SO 2 injection for climate intervention, alumina particle injection could reduce stratospheric warming and associated adverse impacts. However, heterogeneous chemistry on alumina particles, especially chlorine activation via , is poorly constrained under stratospheric conditions, such as low temperature and humidity. This study quantifies the uncertainty in modeling the ozone response to alumina injection. We show that extrapolating the limited experimental data for ClONO 2 + HCl to stratospheric conditions leads to uncertainties in heterogeneous reaction rates of almost two orders of magnitude. Implementation of injection of 5 Mt/yr of particles with 240 nm radius in an aerosol‐chemistry‐climate model shows that resulting global total ozone depletions range between negligible and as large as 9%, that is more than twice the loss caused by chlorofluorocarbons, depending on assumptions on the degree of dissociation and interaction of the acids HCl, HNO 3 , and H 2 SO 4 on the alumina surface.