Quantification of electrogenerated chemiluminescence from tris(bipyridine)ruthenium(<scp>ii</scp>) and hydroxyl ions
Andrea Fiorani, Giovanni Valenti, Irkham Irkham, Francesco Paolucci, Yasuaki Einaga
Abstract
/tri-n-propylamine system, taken as a reference, with relative emission as low as 600 and 230 times that observed at the same coreactant concentration and the same pH, respectively. The kinetics was investigated by foot of the wave analysis of cyclic voltammetry to measure the turnover frequency of the reaction.
Topics & Concepts
RutheniumChemiluminescenceTrisChemistry2,2'-BipyridineIonBipyridinePhotochemistryElectrochemiluminescenceHydroxyl radicalInorganic chemistryRadicalOrganic chemistryElectrodeCatalysisPhysical chemistryBiochemistryCrystal structureElectrochemical Analysis and ApplicationsAdvanced biosensing and bioanalysis techniquesMolecular Junctions and Nanostructures