Solid-state mechanochemical cross-coupling of insoluble substrates into insoluble products by removable solubilizing silyl groups: uniform synthesis of nonsubstituted linear oligothiophenes
Koji Kubota, Keisuke Kondo, Tamae Seo, Mingoo Jin, Hajime Ito
Abstract
We developed a new solid-state mechanochemical strategy using a removable and solubilizing silyl group that enables the organic transformation of insoluble substrates into insoluble products.
Topics & Concepts
SilylationSolid-stateChemistryGroup (periodic table)Transformation (genetics)Coupling (piping)Chemical engineeringMaterials scienceOrganic chemistryComposite materialCatalysisPhysical chemistryGeneBiochemistryEngineeringCrystallography and molecular interactionsAxial and Atropisomeric Chirality SynthesisPolydiacetylene-based materials and applications