Nonmetal-catalyzed hydroamination of ynamides with amines
Yanru Wang, Zhen Zhao, Songkui Lv, Lixia Ding, Xiaona Wang, Junbiao Chang
Abstract
A TfOH-catalyzed hydroamination of ynamides with primary and secondary amines under mild reaction conditions is described for the efficient synthesis of N -arylimines and ethene-1,1-diamines.
Topics & Concepts
HydroaminationChemistryCatalysisNonmetalPrimary (astronomy)Organic chemistryCombinatorial chemistryPhysicsMetalAstronomyCatalytic Alkyne ReactionsCatalytic C–H Functionalization MethodsCyclopropane Reaction Mechanisms