Thermodynamic excess properties of binary mixtures of methanol + pyridine, methanol + benzene, and pyridine + benzene at several temperatures and atmospheric pressure

Abstract

This work reports experimental densities and sound speeds at (293.15, 298.15, 303.15, 308.15, and 313.15) K and viscosities at 298.15 K for the binary liquid mixtures methanol + pyridine, methanol + benzene, and pyridine + benzene over the entire range of compositions and atmospheric pressure. The excess properties, namely the excess molar volume VmE, excess isentropic compressibility κSE, and excess Gibbs energy for activation of viscous flow G*E were calculated from experimental data and are fitted to Redlich-Kister polynomials. The results obtained were discussed in terms of molecular interactions between the mixing components and structural effects.

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