Defect-Engineered Chiral Metal–Organic Frameworks for Efficient Asymmetric Aldol Reaction
Zijuan Chen, Xiaodan Yan, Meiyan Li, Shuhua Wang, Chao Chen
Abstract
By employment of a mixed truncated chiral ligand synthetic strategy, a defect-engineered chiral metal-organic framework with hierarchical micro/mesoporous structure was prepared, and it exhibited efficient heterogeneous catalytic activity and enantioselectivity for asymmetric aldol reaction.
Topics & Concepts
ChemistryAldol reactionMetal-organic frameworkCatalysisEnantioselective synthesisLigand (biochemistry)Mesoporous materialCombinatorial chemistryChiral ligandMetalOrganic chemistryReceptorAdsorptionBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsPolyoxometalates: Synthesis and Applications