Coordination polymers from an unexplored biphenyl-tricarboxylate linker: hydrothermal synthesis, structural traits and catalytic cyanosilylation
Jin‐Zhong Gu, Shi-Mao Wan, Wei Dou, Marina V. Kirillova, Alexander M. Kirillov
Abstract
3,2′,4′-Biphenyl-tricarboxylic acid (H<sub>3</sub>bta) was used as a versatile linker for preparing a new series of metal(<sc>ii</sc>) (Zn, Ni, and Cd) coordination polymers and complexes with notable structural, luminescence and catalytic features.
Topics & Concepts
BiphenylLinkerCatalysisHydrothermal circulationPolymerLuminescenceTricarboxylic acidMaterials scienceMetalChemistryCrystallographyCombinatorial chemistryPolymer chemistryOrganic chemistryChemical engineeringCitric acid cycleOptoelectronicsEnzymeComputer scienceOperating systemEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesOrganometallic Compounds Synthesis and Characterization