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A novel series of dipeptide derivatives containing indole-3-carboxylic acid conjugates as potential antimicrobial agents: the design, solid phase peptide synthesis, <i>in vitro</i> biological evaluation, and molecular docking study

Sunil Tivari, Siddhant V. Kokate, Enrique Delgado‐Alvarado, Manoj Gayke, Amol S. Kotmale, Harun Patel, Iqrar Ahmad, Elizabeth M. Sobhia, Siva G. Kumar, Bianey García Lara, Vicky Jain, Yashwantsinh Jadeja

2023RSC Advances22 citationsDOIOpen Access PDF

Abstract

) were employed for the evaluation of the antifungal activity of the synthesized compounds. When compared to the standard drug Fluconazole, it was observed that the screened analogues exhibited good antifungal activity. In continuation, all the synthesized derivatives were subjected to integrated molecular docking studies and molecular dynamics simulations to investigate binding affinities, intermolecular interaction networks, and conformational flexibilities with deoxyribonucleic acid (DNA) gyrase and lanosterol-14-alpha demethylase. The molecular docking studies revealed that indole-3-carboxylic acid conjugates exhibited encouraging binding interaction networks and binding affinity with DNA gyrase and lanosterol-14 alpha demethylase to show antibacterial and antifungal activity, respectively. Such synthesis, biological activity, molecular dynamics simulations, and molecular docking studies of short peptides with an indole conjugate unlock the door for the near future advancement of novel medicines containing peptide-heterocycle hybrids with the ability to be effective as antimicrobial agents.

Topics & Concepts

DipeptideChemistryPeptideIndole testCombinatorial chemistryConjugateAntimicrobialConjugated systemSolid-phase synthesisPeptide synthesisCarboxylic acidIn vitroDocking (animal)StereochemistryOrganic chemistryBiochemistryPolymerMathematical analysisMathematicsMedicineNursingAntimicrobial Peptides and ActivitiesChemical Synthesis and AnalysisBiochemical and Structural Characterization
A novel series of dipeptide derivatives containing indole-3-carboxylic acid conjugates as potential antimicrobial agents: the design, solid phase peptide synthesis, <i>in vitro</i> biological evaluation, and molecular docking study | Litcius