Correlative non-destructive techniques to investigate aging and orientation effects in automotive Li-ion pouch cells
Arthur Fordham, Zoran Milojević, Emily Giles, Wenjia Du, Rhodri E. Owen, Š. Michalik, Philip A. Chater, Prodip K. Das, Pierrot S Attidekou, Simon Lambert, Phoebe K. Allan, Peter R. Slater, Paul A. Anderson, Rhodri Jervis, Paul R. Shearing, Dan J. L. Brett
Abstract
The growing demand for electric vehicles (EVs) continues to raise concern for the disposal of lithium-ion batteries reaching their end of life (EoL). The cells inside EVs age differently depending on multiple factors. Yet, following extraction, there are significant challenges with characterizing degradation in cells that have been aged from real-world EV usage. We employed four non-destructive techniques—infrared thermography, ultrasonic mapping, X-ray tomography, and synchrotron X-ray diffraction—to analyze the aging of Nissan Leaf large-format pouch cells that were arranged in different orientations and locations within the pack. The combination of these methods provided complementary insights into cell degradation, with rotated/vertically aligned cells exhibiting distinct aging patterns compared with flat/horizontally aligned cells. These findings offer valuable information for pack design and demonstrate how cost-effective non-destructive techniques can provide practical assessment capabilities comparable to synchrotron studies. This approach enables decision support during EoL, enhancing battery production efficiency and minimizing material waste.