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Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets

Xinpeng Chen, Xinpeng Chen, Xiangdong Chen, Xiangdong Chen, Xing Ding, Xiang Yu

2022Chemosensors17 citationsDOIOpen Access PDF

Abstract

In this work, hydrochloric acid (HCl)-doped molybdenum ditelluride (MoTe2) nanosheets/polyaniline (PANI) nanofiber composites are prepared by in situ chemical oxidation polymerization, and then the composites are deposited on interdigital electrodes (IDEs) to fabricate a NH3 gas sensor. Morphological analysis of the composites reveals that the PANI fibers are deposited on 2D MoTe2 sheets, showing a porous mesh microstructure structure with a more continuous distribution of PANI layer. FTIR spectrum analysis indicates the interaction between the MoTe2 nanosheets and the PANI in the MoTe2/PANI composites. The results demonstrate that the as-prepared MoTe2/PANI composites exhibit higher response than the pure PANI, in particular, the 8 wt.% MoTe2/PANI composites display about 4.23 times enhancement in response value toward 1000 ppm NH3 gas compared with the pure PANI. The enhanced NH3 gas-sensitive properties may be due to the increasing surface area of MoTe2/PANI composite films and the possible interaction of the P-N heterojunctions formed between PANI and the 2H-MoTe2 nanosheets.

Topics & Concepts

PolyanilineMaterials scienceMolybdenumPolymerizationMicrostructureComposite materialComposite numberChemical engineeringFourier transform infrared spectroscopyMolybdenum disulfideIn situ polymerizationHeterojunctionHydrochloric acidPolymerMetallurgyOptoelectronicsEngineeringGas Sensing Nanomaterials and SensorsConducting polymers and applicationsAdvanced Sensor and Energy Harvesting Materials
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