A nickel-based metal–organic framework as a new cathode for chloride ion batteries with superior cycling stability
Qing Yin, Zhihao Song, Shuhan Yang, Gang‐Ding Wang, Yanwei Sui, Jiqiu Qi, Danyang Zhao, Lei Hou, Yong‐Zhi Li
Abstract
average diffusion coefficient for chloride ions as well. The high performance of the Ni(dpip) cathode results from the synergetic redox couples of Ni metal nodes and N-ligands, the unique double-channel structure for reversible Cl-storage, and the low chloride diffusion energy barrier. This work switches on the new application of MOF-based materials as cathodes for CIBs.
Topics & Concepts
CathodeChlorideMaterials scienceNickelIonEnergy storageDiffusionChemical engineeringRedoxMetal-organic frameworkNanotechnologyChemistryPhysical chemistryMetallurgyThermodynamicsOrganic chemistryPower (physics)AdsorptionEngineeringPhysicsInorganic Fluorides and Related CompoundsAdvancements in Battery MaterialsAdvanced Battery Materials and Technologies