Visible-light-induced direct perfluoroalkylation/heteroarylation of [1.1.1]propellane to diverse bicyclo[1.1.1]pentanes (BCPs) under metal and photocatalyst-free conditions
Jiashun Zhu, Yirui Guo, Yu‐Ru Zhang, Wanmei Li, Pengfei Zhang, Jun Xu
Abstract
This study describes a green and novel multi-component reaction for direct perfluoroalkylation/heteroarylation of [1.1.1]propellane with heteroarenes and perfluoroalkyl iodines to diverse bicyclo[1.1.1]pentanes (BCPs).
Topics & Concepts
PropellanePhotocatalysisBicyclic moleculeChemistryMetalPhotochemistryOrganic chemistryCatalysisFluorine in Organic ChemistryRadical Photochemical ReactionsSulfur-Based Synthesis Techniques