Litcius/Paper detail

High-Throughput Screening of COF Membranes and COF/Polymer MMMs for Helium Separation and Hydrogen Purification

Sena Aydin, Çiğdem Altıntaş, Seda Keskın

2022ACS Applied Materials & Interfaces93 citationsDOIOpen Access PDF

Abstract

separations. Both real and hypothetical COFs were then studied as fillers in 25 different polymers, leading to a total of 29 020 COF/polymer and hypoCOF/polymer mixed matrix membranes (MMMs), representing the largest number of COF-based MMMs investigated to date. Permeabilities and selectivities of COF/polymer MMMs were computed for six different gas separations, and results revealed that 18 of the 25 polymers can be carried above the upper bound when COFs were used as fillers. The comprehensive analysis of COFs provided in this work will fully unlock the potential of COF membranes and COF/polymer MMMs for helium separation and hydrogen purification.

Topics & Concepts

Materials scienceMembraneSeparation (statistics)PolymerThroughputHydrogenGas separationChemical engineeringHeliumNanotechnologyOrganic chemistryComposite materialComputer scienceWirelessChemistryEngineeringMachine learningGeneticsBiologyTelecommunicationsMembrane Separation and Gas TransportHydrogen Storage and MaterialsMembrane-based Ion Separation Techniques