Electrosynthesis of Quinazolines and Quinazolinones via an Anodic Direct Oxidation C(sp<sup>3</sup>)-H Amination/C-N Cleavage of Tertiary Amine in Aqueous Medium
Zhenghong Zhou, Kangfei Hu, Jiawei Wang, Zhibin Li, Yan Zhang, Zhenggen Zha, Zhiyong Wang
Abstract
)-H amination/C-N cleavage by virtue of the anodic oxidation. The reaction can be carried out in aqueous media under mild conditions to afford the desired products with high yields. The reaction mechanism was proposed after detailed investigation.
Topics & Concepts
ElectrosynthesisAminationAmine gas treatingChemistryCleavage (geology)ElectrochemistryAqueous solutionAnodeAqueous mediumCombinatorial chemistryOrganic chemistryCatalysisElectrodeMaterials sciencePhysical chemistryFracture (geology)Composite materialQuinazolinone synthesis and applicationsRadical Photochemical ReactionsCatalytic C–H Functionalization Methods