Zinc-catalyzed transamidation and esterification of <i>N</i>-benzoyl cytosine <i>via</i> C–N bond cleavage
Sujeet Gaware, Rana Chatterjee, Anant R. Kapdi, Rambabu Dandela
Abstract
catalytic C-N bond cleavage. The one-pot strategy involves the reaction of secondary amide with various aliphatic or aromatic amines and alcohols in the presence of zinc triflate and DTBP, affording diverse amides and esters in excellent yields.
Topics & Concepts
CatalysisCleavage (geology)ChemistryZincBond cleavageCytosineMedicinal chemistryStereochemistryOrganic chemistryDNABiochemistryBiologyFracture (geology)PaleontologyChemical Synthesis and AnalysisOrganoboron and organosilicon chemistryClick Chemistry and Applications