Inorganic–organic {d<sub><i>z</i><sup>2</sup></sub>-M<sup>II</sup>S<sub>4</sub>}⋯π-hole stacking in reverse sandwich structures: the case of cocrystals of group 10 metal dithiocarbamates with electron-deficient arenes
Лев Е. Зеленков, Anastasiya A. Eliseeva, Sergey V. Baykov, Daniil M. Ivanov, Alina I. Sumina, Rosa M. Gomila, Antonio Frontera, Vadim Yu. Kukushkin, Nadezhda A. Bokach
Abstract
The {d z 2 -M II S 4 } (M = Ni, Pd, Pt) moieties function as integrated five-center acceptors toward a π-hole of an electron-deficient arene furnishing the reverse sandwich structures.
Topics & Concepts
StackingCrystallographyCenter (category theory)Group (periodic table)ChemistryMaterials sciencePhysicsNuclear magnetic resonanceOrganic chemistryCrystallography and molecular interactionsOrganometallic Compounds Synthesis and CharacterizationInorganic Fluorides and Related Compounds