Low-Temperature NH3-SCR Performance and In Situ DRIFTS Study on Zeolite X-Supported Different Crystal Phases of MnO2 Catalysts
Lin Chen, Shan Ren, Tao Chen, Xiaodi Li, Mingming Wang, Zhichao Chen, Qingcai Liu
Abstract
In this study, a series of zeolite-X-supported different crystal phases of MnO2 (α-MnO2, β-MnO2, γ-MnO2, and σ-MnO2) catalysts were prepared via a solid-state diffusion method and high-heat treatment method to explore their low-temperature NH3-SCR performance. All of the catalysts featured typical octahedral zeolite X structures and manganese dioxides species of various crystal types dispersed across the support surface. Throughout the entire temperature range of the reaction, γ-MnO2/X catalyst had the highest NO conversion. Additionally, β-MnO2/X, γ-MnO2/X, and σ-MnO2/X catalysts had nearly 100% of N2 selectivity, whereas the α-MnO2/X catalyst had the lowest N2 selectivity (about 90%) below 125 °C. Moreover, the γ-MnO2/X catalyst demonstrated superior acidity capacity and reduction ability compared with the other three catalysts. All the catalysts contained the essential intermediates NH2NO and NH4NO3 species, which are essential to the SCR reaction. More acid sites and nitrate species existed on the γ-MnO2/X catalyst than on the other catalysts, thereby boosting the SCR reaction.