Unraveling the timescale of the structural photo-response within oriented metal–organic framework films
Sumea Klokić, Denys Naumenko, Benedetta Marmiroli, Francesco Carraro, Mercedes Linares‐Moreau, Simone Dal Zilio, Giovanni Birarda, Rupert Kargl, Paolo Falcaro, Heinz Amenitsch
Abstract
, 450 nm). Within seconds, the DMOF-1/AB response occurred fully reversible and over several switching cycles by cooperative photo-switching of the oriented DMOF-1/AB crystallites as confirmed further by infrared measurements. Our work thereby suggests a new avenue to elucidate the timescales and photo-switching characteristics in structurally responsive MOF film systems.
Topics & Concepts
AzobenzeneIsomerizationMaterials scienceCrystalliteMetal-organic frameworkInfraredOptoelectronicsChemical physicsNanotechnologyOpticsChemistryPolymerAdsorptionPhysical chemistryComposite materialPhysicsCatalysisOrganic chemistryMetallurgyMetal-Organic Frameworks: Synthesis and ApplicationsNanoplatforms for cancer theranosticsAdvanced Nanomaterials in Catalysis