Selective Manganese-Catalyzed Dimerization and Cross-Coupling of Terminal Alkynes
Stefan Weber, Luı́s F. Veiros, Karl Kirchner
Abstract
-1,3-enynes. In all cases, the reactions were performed at 70 °C with a catalyst loading of 1-2 mol %. A mechanism based on density functional theory (DFT) calculations is presented.
Topics & Concepts
CatalysisAlkyneAcetylideChemistryManganeseAlkylTriple bondYield (engineering)Bond cleavageLigand (biochemistry)Medicinal chemistryPolymer chemistryPhotochemistryOrganic chemistryDouble bondMaterials scienceMetallurgyBiochemistryReceptorCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsAsymmetric Hydrogenation and Catalysis