Planar-chiral arene ruthenium complexes: synthesis, separation of enantiomers, and application for catalytic C–H activation
Mikhail A. Boym, Roman A. Pototskiy, Evgeniya Podyacheva, Denis Chusov, Yulia V. Nelyubina, Dmitry S. Perekalin
Abstract
The enantiomers of an arene ruthenium complex were separated by chromatography using auxiliary chiral phosphine. The resolved planar-chiral complex catalyzed asymmetric C–H activation of N -methoxy-benzamides.
Topics & Concepts
RutheniumEnantiomerCatalysisCombinatorial chemistryPlanarChemistryEnantioselective synthesisStereochemistryOrganic chemistryComputer scienceComputer graphics (images)Catalytic C–H Functionalization MethodsAsymmetric Hydrogenation and CatalysisSynthesis and Catalytic Reactions