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Lights and Shadows of DMSO as Solvent for Tin Halide Perovskites

Jorge Pascual, Diego Di Girolamo, Marion A. Flatken, Mahmoud H. Aldamasy, Guixiang Li, Meng Li, Antonio Abate

2021Chemistry - A European Journal44 citationsDOIOpen Access PDF

Abstract

. Nonetheless, alternatives are lacking and few efforts have been devoted to replacing it. To understand this trend it is indispensable to learn the importance of DMSO on the development of tin halide perovskites. Its unique properties have allowed processing compact thin-films to be integrated into tin perovskite solar cells. Creative approaches for controlling the perovskite crystallization or increasing its stability to oxidation have been developed relying on DMSO-based inks. However, increasingly sophisticated strategies appear to lead the field to a plateau of power conversion efficiency in the range of 10-15 %. And, while DMSO-based formulations have performed in encouraging means so far, we should also start considering their potential limitations. In this concept article, we discuss the benefits and limitations of DMSO-based tin perovskite processing.

Topics & Concepts

TinHalidePerovskite (structure)SolventCrystallizationMaterials scienceNucleationNanotechnologyDimethyl sulfoxideChemical engineeringInorganic chemistryChemistryOrganic chemistryMetallurgyEngineeringPerovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyOrganic and Molecular Conductors Research
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