Nonacethrene Unchained: A Cascade to Chiral Contorted Conjugated Hydrocarbon with Two sp <sup>3</sup> -Defects
Daniel Čavlović, Daniel Häußinger, Olivier Blacque, Prince Ravat, Michal Jurı́ček
Abstract
. Our results show that reactions of graphene-based π-radicals-typically considered an "undefined decomposition" of non-zero-spin materials-can be well-defined and selective, and have potential to be transformed into a step-economic synthetic method toward complex carbon nanostructures.
Topics & Concepts
ChemistryPhotochemistryRadicalQuantum yieldCascade reactionConjugated systemReaction intermediateYield (engineering)PorphyrinRing (chemistry)FluorescenceCrystallographyMaterials scienceCatalysisOrganic chemistryMetallurgyQuantum mechanicsPolymerPhysicsSynthesis and Properties of Aromatic CompoundsAdvanced NMR Techniques and ApplicationsFullerene Chemistry and Applications