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Synthesis of fused energetic compounds using structural modification from local carbonyl to hydroxylamine/hydrazone

Caijin Lei, Chuan Xiao, Jie Tang, Hongwei Yang, Qinghua Zhang, Guangbin Cheng

2023Chemical Communications12 citationsDOI

Abstract

This work presents the successful synthesis of a series of fused energetic compounds using the strategy of structural modification from local carbonyl to hydroxylamine, hydrazone or methylamine. Hydroxylamine-substituted compound 2 exhibits high density, high detonation performance and low sensitivities as a secondary explosive.

Topics & Concepts

HydrazoneHydroxylamineChemistryOrganic chemistryCombinatorial chemistryEnergetic Materials and CombustionRocket and propulsion systems researchThermal and Kinetic Analysis
Synthesis of fused energetic compounds using structural modification from local carbonyl to hydroxylamine/hydrazone | Litcius