Electrosynthesis of a hyperbranched dendrimeric porphyrin polymer: optical and electronic characterization as a material for bifunctional electrochromic supercapacitors
Javier E. Durantini, Raúl Rubio, Claudia Solís, Lorena Macor, Gustavo M. Morales, María I. Mangione, Daniel A. Heredia, Edgardo N. Durantini, Luís Otero, Miguel Gervaldo
Abstract
A hyperbranched polymeric conducting film was generated by electrochemical polymerization of a Zn(<sc>ii</sc>) porphyrin monomer. The polymer presents adequate electronic properties for application in electrochromic and energy storage devices.
Topics & Concepts
ElectrochromismBifunctionalElectrosynthesisPorphyrinMaterials scienceElectrochromic devicesMonomerSupercapacitorPolymerizationPolymerElectrochemistryPolymer chemistryPrussian blueChemical engineeringOrganic chemistryChemistryElectrodeComposite materialPhysical chemistryCatalysisEngineeringConducting polymers and applicationsCovalent Organic Framework ApplicationsLuminescence and Fluorescent Materials