A novel molecular descriptor for highly efficient (ϕTADF > 90%) transition metal TADF Au(<scp>iii</scp>) complexes

Yu Wang, Qian Peng, Qi Ou, Shiyun Lin, Zhigang Shuai

2020Journal of Materials Chemistry A33 citationsDOI

Abstract

It is generally perceived that a fast reverse intersystem crossing rate of T1 → S1 (<italic>k</italic>risc) is crucial for efficient organic thermally activated delayed fluorescence (TADF) emitters.

Topics & Concepts

Intersystem crossingFluorescenceTransition metalMaterials sciencePhysicsChemistryAtomic physicsCatalysisExcited stateOpticsBiochemistrySinglet stateOrganic Light-Emitting Diodes ResearchMagnetism in coordination complexesLanthanide and Transition Metal Complexes

A novel molecular descriptor for highly efficient (<i>ϕ</i><sub>TADF</sub> &gt; 90%) transition metal TADF Au(<scp>iii</scp>) complexes

Abstract

Topics & Concepts

A novel molecular descriptor for highly efficient (<i>ϕ</i><sub>TADF</sub> > 90%) transition metal TADF Au(<scp>iii</scp>) complexes