Enantioselective Intermolecular C–H Amination Directed by a Chiral Cation
Alexander Fanourakis, Benjamin D. Williams, Kieran Paterson, Robert J. Phipps
Abstract
and highlighting the dual role that the cation is playing. These results underline the potential of using chiral cations to control enantioselectivity in challenging transition-metal-catalyzed transformations.
Topics & Concepts
ChemistryEnantioselective synthesisAminationIntermolecular forceOrganic chemistryStereochemistryCombinatorial chemistryCatalysisMoleculeSynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsAsymmetric Synthesis and Catalysis