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NaZr<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> – a cubic langbeinite-type sodium-ion solid conductor

Sergey N. Marshenya, Alexey G. Scherbakov, Artem D. Dembitskiy, Alexander A. Golubnichiy, Ivan A. Trussov, Aleksandra A. Savina, С. М. Казаков, Dmitry A. Aksyonov, Evgeny V. Antipov, Stanislav S. Fedotov

2024Dalton Transactions10 citationsDOI

Abstract

The synthesis of a cubic langbeinite NaZr 2 (PO 4 ) 3 via an ion exchange reaction supported by mechanochemical activation is described. The crystal structure and Na transport properties are studied. HT XRD reveals negative thermal expansion.

Topics & Concepts

IonSodiumConductorIon exchangeChemistryCrystallographyCubic crystal systemCrystal (programming language)Crystal structureMaterials scienceInorganic chemistryAnalytical Chemistry (journal)Composite materialComputer scienceProgramming languageChromatographyOrganic chemistryThermal Expansion and Ionic ConductivityAdvanced Battery Materials and TechnologiesAdvancements in Battery Materials
NaZr<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> – a cubic langbeinite-type sodium-ion solid conductor | Litcius