Heterolytic carbon–iodine bond cleavage by a palladium(<scp>i</scp>) metalloradical
Matthew J. G. Sinclair, Adrian B. Chaplin
Abstract
and phosphonium salts. Pd(II) aryl/alkyl derivates, reflecting net radical oxidative addition of the substrate to the metalloradical, are generated during the reaction and two examples have been isolated and crystallographically characterised.
Topics & Concepts
HeterolysisArylChemistryAlkylPhosphoniumPalladiumIodineMedicinal chemistryOxidative additionCleavage (geology)Substrate (aquarium)Bond cleavageIodine compoundsPolymer chemistryPhotochemistryOrganic chemistryCatalysisMaterials scienceGeologyComposite materialFracture (geology)OceanographyCoordination Chemistry and OrganometallicsCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization Methods