Multiple chirality inversion of pyridine Schiff-base cholesterol-based metal–organic supramolecular polymers
Yanbin Wang, Chongtao Liu, Kuo Fu, Junxi Liang, Shaofeng Pang, Guofeng Liu
Abstract
Based on coordination driven co-assembly strategy, metal–organic supramolecular polymers of pyridine Schiff-base cholesterol and silver ion with tunable supramolecular chirality inversion was successfully achieved by the stoichiometry and solvent polarity.
Topics & Concepts
Schiff baseSupramolecular chemistryPyridineChirality (physics)Supramolecular chiralityMetalPolymerPolymer chemistryInversion (geology)ChemistryMaterials scienceCrystallographyOrganic chemistryCrystal structurePhysicsBiologyNambu–Jona-Lasinio modelQuarkStructural basinQuantum mechanicsChiral symmetry breakingPaleontologySupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applicationsMolecular Sensors and Ion Detection