Enantiopure nanohoops through racemic resolution of diketo[<i>n</i>]CPPs by chiral derivatization as precursors to DBP[<i>n</i>]CPPs
Daniel Wassy, Mathias Hermann, Jan S. Wössner, Lucas Frédéric, Grégory Pieters, Birgit Esser
Abstract
Racemic resolution of diketone-embedded cycloparaphenylenes by derivatization with a chiral auxiliary provides scalable access to enantiopure hoops with chiroptical properties.
Topics & Concepts
Enantiopure drugDerivatizationChemistryResolution (logic)Chiral derivatizing agentCombinatorial chemistryChiral resolutionOrganic chemistryEnantiomerEnantioselective synthesisChiral column chromatographyHigh-performance liquid chromatographyCatalysisComputer scienceArtificial intelligenceSynthesis and Properties of Aromatic CompoundsAxial and Atropisomeric Chirality SynthesisSupramolecular Self-Assembly in Materials