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Fabrication of high‐efficiency Yb:Y <sub>2</sub> O <sub>3</sub> laser ceramics without photodarkening

Qing Li, Jun Wang, Jie Ma, Meng Ni, Fan Yang, Peng Liu, Kuo Yang Lee, Hsing‐I Hsiang, Deyuan Shen, Dingyuan Tang

2022Journal of the American Ceramic Society28 citationsDOI

Abstract

Abstract High‐efficiency Yb:Y 2 O 3 laser ceramics were fabricated using the vacuum‐sintering plus hot isostatic pressing (HIP) without sintering additives. High‐purity well‐dispersed nanocrystalline Yb:Y 2 O 3 powder was synthesized using a modified co‐precipitation method in‐house. The green bodies were first vacuum sintered at a temperature as low as 1430°C and then HIPed at 1450°C. Finally, the samples were air annealed at 800°C for 10 h. Although no sintering aids were used, full density of the samples with excellent optical homogeneity and an inline transmission of 80% at 400 nm could be obtained. Moreover, photodarkening phenomenon was not detected in the ceramics. Preliminary laser experiment with the fabricated ceramics in a two‐mirror cavity has demonstrated 32 W continuous‐wave (CW) output at ∼1077 nm with an optical‐to‐optical conversion efficiency of 58.2%. To the best of our knowledge, this is so far the highest CW output power and optical‐to‐optical conversion efficiency achieved with the Yb 3+ ‐doped sesquioxide ceramics in a simple two‐mirror cavity.

Topics & Concepts

Materials scienceHot isostatic pressingPhotodarkeningCeramicTransparent ceramicsSesquioxideSinteringSlope efficiencyFabricationLaserOpticsOptoelectronicsAnalytical Chemistry (journal)MineralogyComposite materialMetallurgyWavelengthFiber laserPhysicsChemistryAlternative medicineChromatographyMedicinePathologySolid State Laser TechnologiesLuminescence Properties of Advanced MaterialsGlass properties and applications