A neutral vicinal silylene/phosphane supported six-membered C<sub>2</sub>PSiAu<sub>2</sub> ring and a silver(<scp>i</scp>) complex
Mohd Nazish, Han Bai, Christina M. Legendre, Regine Herbst‐Irmer, Lili Zhao, Dietmar Stalke, Herbert W. Roesky
Abstract
We report on the hybrid bidentate silylene and phosphane ligand (1) stabilized Au which are capable of forming a gold containing six-membered ring (2). 2 exhibits an intramolecular aurophilic interaction, which is supported by DFT calculations.
Topics & Concepts
ChemistryIntramolecular forceRing (chemistry)DenticityMoleculeAdductDichloromethaneCrystallographyLigand (biochemistry)Silver saltsSilyleneFluorineStereochemistryInorganic chemistryOrganic chemistryCrystal structureReceptorBiochemistrySiliconSolventOrganometallic Complex Synthesis and CatalysisSynthesis and characterization of novel inorganic/organometallic compoundsN-Heterocyclic Carbenes in Organic and Inorganic Chemistry