A zinc porphyrin-based halogen-bonded organic framework with the heavy atom effect as a highly efficient photocatalyst for oxidative coupling of amines
Penghao Sun, Hongqiang Dong, Siheng Lv, Yongfei Yin, Guanfei Gong, Lu Wang, Jike Wang, Shigui Chen
Abstract
A novel zinc porphyrin-based [N⋯I + ⋯N] halogen-bonded organic framework has high photocatalytic 1 O 2 yields, which results from the heavy atom effect of the I + , and acts as a highly efficient photocatalyst for organic synthesis.
Topics & Concepts
PorphyrinHalogenPhotocatalysisZincAtom (system on chip)PhotochemistryChemistryMaterials scienceOrganic chemistryCatalysisEmbedded systemComputer scienceAlkylMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsAdvanced Photocatalysis Techniques