KOH-Induced Oxygen-Deficient VO<sub>2</sub> for High-Rate Aqueous Zn-Ion Batteries
Guangxu Yang, Shuhua Yang, Jian Shen, Yanwei Cui, Jinfeng Sun, Guangbin Duan, Bingqiang Cao, Zongming Liu
Abstract
Due to its high safety and low cost, aqueous Zn-ion batteries (AZIBs) have become one of the most promising energy storage devices. However, the development of a stable cathode with fast kinetics and high-energy density is crucial to realize AZIBs for large-scale application. In this work, KOH-induced oxygen-deficient VO 2 (K-VO 2 ) was developed by activating doughnutlike VO 2 by KOH. Benefiting from the combination of a unique morphology with abundant active sites and the oxygen vacancy, increasing the interlayer spacing, both improved kinetics and enhanced Zn-ion storage capability in the VO 2 cathode are achieved. The optimized K-VO 2 -3:4 delivers a specific capacity of 260.9 mA h g –1 at 0.2 A g –1, an excellent high-rate capability of 166.1 mA h g –1 at 5 A g –1, and long-term cyclic stability with a capacity retention of 88.1% after 3000 cycles. The electrochemical performance of K-VO 2 -3:4 has been greatly improved compared with untreated VO 2 . The KOH activation strategy proposed here also presents an encouraging pathway for developing other high-energy and stable cathodes.