Single crystal structure and photocatalytic behavior of grafted uranyl on the Zr-node of a pyrene-based metal–organic framework
Julia G. Knapp, Xuan Zhang, Tatyana Elkin, Laura E. Wolfsberg, Sylvia L. Hanna, Florencia A. Son, Brian L. Scott, Omar K. Farha
Abstract
The zirconium MOF NU-1000 was post-synthetically modified through solvothermal deposition to include the uranyl ion and characterized<italic>via</italic>single-crystal X-ray diffraction; photo-oxidation was also performed.
Topics & Concepts
UranylZirconiumPhotocatalysisMaterials scienceUraniumMetal-organic frameworkPyreneMetalSingle crystalCrystal structureInorganic chemistryPhotochemistryCrystallographyChemistryOrganic chemistryCatalysisMetallurgyAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsRadioactive element chemistry and processingNuclear Materials and Properties